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alpha cypermethrin

Alpha-cypermethrin

CAS: 67375-30-8

Molecular Formula: C22H19Cl2NO3

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alpha cypermethrin - Names and Identifiers

Name Alpha-cypermethrin
Synonyms Fastac
Bestox
WL 85871
alphametrin
Alphamethrin
α-Cypermethrin
Alphacypermethrin
alpha cypermethrin
Alpha-cypermethrin
cyano-3-phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane carboxylate
2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate-α-cyano-(3-phenoxy)-benzylester
cyano(3-phenoxyphenyl)methyl (1R,3R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
Cyano-3-phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, (+-)-cis isomer
Cyano(3-phenoxyphenyl)methyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, (+-)-cis isomer
Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, cyano(3-phenoxyphenyl)methyl ester, (S)-
cyano(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate, (1A(S*), 3A)-(+-)-
CAS 67375-30-8
InChI InChI=1/2C22H19Cl2NO3/c2*1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-4-3-5-9-15/h2*3-12,17-18,20H,1-2H3/t2*17-,18+,20-/m10/s1

alpha cypermethrin - Physico-chemical Properties

Molecular FormulaC22H19Cl2NO3
Molar Mass416.3
Density1.12
Melting Point78-81℃
Boling Point826°C at 760 mmHg
Flash Point453.3°C
Water Solubility0.01 mg l-1 (25 °C)
Vapor Presure2.03E-27mmHg at 25°C
Storage Condition2-8℃
Refractive Index1.6200 (estimate)
Physical and Chemical PropertiesThe pure chemical properties are white to cream crystals. M. p.80.5 ℃, relative density 1.12, vapor pressure 170 × 10-6Pa at 20 ℃. Soluble in alcohols, ketones and aromatic hydrocarbon organic solvents, such as cyclohexanone 515g/L, xylene 315g/L, solubility in water 5~10mg/L (0.01~0.2mg/L). It is stable under acidic and neutral conditions, easy to hydrolyze under strong alkaline conditions, and has good thermal stability.
UseWidely used in the control of cotton, fruit, soybean, vegetables and other crops of Lepidoptera, Coleoptera and binocular pests

alpha cypermethrin - Risk and Safety

Hazard SymbolsT - Toxic
Toxic
N - Dangerous for the environment
Dangerous for the environment
Risk CodesR25 - Toxic if swallowed
R37 - Irritating to the respiratory system
R48/22 - Harmful danger of serious damage to health by prolonged exposure if swallowed.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
Safety DescriptionS36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
UN IDsUN 2811

alpha cypermethrin - Upstream Downstream Industry

Raw MaterialsSodium cyanide
Hydrochloric acid
Ethyl Alcohol

alpha cypermethrin - Nature

storage conditions Sealed in dry,2-8°C
water solubility 0.01 mg l-1 (25 °C)
morphology neat
BRN 8444118
stability Stable. Incompatible with strong oxidizing agents.
EPA chemical information .alpha.-Cypermethrin (67375-30-8)
Last Update:2024-04-10 22:29:15

alpha cypermethrin - Uses and synthesis methods

use

1, cypermethrin high-efficiency isomer. It has the effects of contact and stomach toxicity, wide insecticidal spectrum, fast knockout rate and high biological activity. It is mainly used to control various crop pests and sanitary pests on cotton, vegetables, fruit trees and tea. 4.5% emulsifiable concentrate 336~666mL (active ingredient 15~30g)/hm2 was used to control cotton aphid and 600 ~ 700L of water was sprayed evenly. Control of cotton bollworm and cotton red bollworm during the incubation period of the 2. three generations of eggs, with 4.5% emulsifiable concentrate 336~666mL (active ingredient 15~30g)/hm2 to 750 ~ 900L of water evenly spray. Control of rapeseed aphid, cabbage worm and diamondback moth with 4.5% emulsifiable concentrate 200~560mL (active ingredient 9~25g)/hm2 to spray 600 ~ 750L of water evenly. For the control of houseflies and mosquitoes, 0.2~0.4g (active ingredient 9~18mg) of. 5% wettable powder is used to spray 250 times of water per square meter. Control cockroaches per square meter with 4.5% wettable powder 0.9g (effective ingredient 40.5mg) to 250~300 times the water spray.

2. Lepidoptera, Coleoptera and Binocular Pests Widely Used to Control Cotton, Fruit Trees, Soybeans, Vegetables and Other Crops

production method

using dichlorochrysanthemum acid (cis inverse ratio is 3/7) as the starting material, cis chrysanthemum acid (content> 93%, cis inverse ratio is 8/2) is obtained after cis-trans separation, cis-cypermethrin is synthesized by ether aldehyde-acyl chloride method, the content is 82%, and then epimerized to obtain high-efficiency cis-cypermethrin, the content is 92%, or α. And realize the process of converting β-body into α-body epimers, eliminating the steps of cis-trans isomer separation of dichlorochrysanthemum acid stereoselective synthesis. See "Pesticide Translation Collection", 1991,13(6):35.

category

Pesticides

toxicity classification

High toxicity

acute toxicity

oral-rat LD50: 79 mg/kg

flammability hazard characteristics

Flammable; combustion produces toxic chloride and nitrogen oxide gas

storage and transportation features

The warehouse is ventilated and dry at low temperature; stored and transported separately from food raw materials

fire extinguishing agent

Dry powder, foam, sand

Last Update:2024-04-10 22:29:15

alpha cypermethrin - Security information

WGK Germany 3
RTECS number GZ1250000
HazardClass 6.1( B )
PackingGroup III
toxic substance data 67375-30-8(Hazardous Substances Data)
Last Update:2024-04-09 15:16:16
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View History
alpha cypermethrin
(+)-DIP chloride
CYCLOOCTAAMYLOSE
Raw Materials for alpha cypermethrin
Sodium cyanide
Hydrochloric acid
Ethyl Alcohol
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